Product ID:3-AMINO-1,2,4-TRIAZOLE, A8056
MSDS Date:04/10/1995
FSC:6810
NIIN:00N062713
MSDS Number: BYVFR

SIGMA CHEMICAL CO

SAINT LOUIS, MO 63178
US

Emergency Phone: 314-771-5765

Info Phone: 800-325-3010

Cage: 0DK69

SIGMA CHEMICAL CO SIGMA DIAGNOSTICS DIV

ST LOUIS, MO 63103-2530 US

Telephone: 314-771-5765

Cage: 0DK69

S-TRIAZOLE, 3-AMINO-; (AMITROLE) (SARA 313) (CERCLA)

CAS: 61-82-5

RTECS: XZ3850000

OSHA PEL 0.2 MG/M3

ACGIH TLV: 0.2 MG/M3

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

LD50 LC50 Mixture:LD50(ORAL,RAT):1100 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:HARMFUL IF SWALLOWED, INHALED, OR
ABSORBED THROUGH SKIN. CAUSES EYE AND SKIN IRRITATION. MATERIAL IS
IRRITATING TO MUCOUS MEMBRANES AND UPPER RESPIRATORY TRACT.
CHRONIC:MAY ALTER GENETIC MATERIAL. TAR GET ORGAN(S):LIVER,
KIDNEYS.
Explanation of Carcinogenicity:S-TRIAZOLE, 3-AMINO (AMITROLE):IARC
MONOGRAPHS, SUPP, VOL 7, PG 92, 1987:GROUP 2B. NTP 7TH ANNUAL RPT
ON (SUP DAT)
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:IN CASE OF ACCIDENT/IF YOU FEEL UNWELL, SEEK MED ADVICE IMMED
(SHOW LBL WHERE POSS). EYES:IMMED FLUSH W/COPIOUS AMTS OF WATER FOR
@ LST 15 MIN. SKIN:IMMED FLUSH W/COPIOUS AMTS OF WATER FOR @ LST 15
MI N WHILE REMOVING CONTAM CLTHG & SHOES. DISCARD CONTAM CLTHG &
SHOES. INHAL:REMOVE TO FRESH AIR. IF NOT BRTHG, GIVE ARTF RESP. IF
BRTHG IS DFCLT, GIVE OXYG. INGEST:WASH OUT MOUTH W/WATER(SUPP DATA)

Extinguishing Media:WATER SPRAY, CARBON DIOXIDE, DRY CHEMICAL POWDER OR
APPROPRIATE FOAM.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT TO PREVENT CONTACT WITH SKIN AND EYES.
Unusual Fire/Explosion Hazard:EMITS TOXIC FUMES UNDER FIRE CONDITIONS.

Spill Release Procedures:EVACUATE AREA. WEAR NIOSH/MSHA APPRVD SCBA,
RUBBER BOOTS & HEAVY RUBBER GLOVES. WEAR DISPOSABLE COVERALLS AND
DISCARD THEM AFTER USE. SWEEP UP, PLACE IN BAG AND HOLD FOR WASTE
DISP. VENTILATE AREA AND WASH SPILL SITE AFTER MATL PICKUP IS
COMPLETE.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:DO NOT BREATHE DUST. AVOID ALL
CONTACT. HARMFUL SOLID. CARCINOGEN. IRRITANT. MUTAGEN. KEEP TIGHTLY
CLOSED. STORE IN A COOL, DRY PLACE.
Other Precautions:NONE SPECIFIED BY MANUFACTURER.

Respiratory Protection:WEAR APPROPRIATE NIOSH/MSHA APPROVED RESPIRATOR.
Ventilation:USE ONLY IN A CHEMICAL FUME HOOD.
Protective Gloves:CHEMICAL RESISTANT GLOVES.
Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS .
Other Protective Equipment:ANSI APPROVED SAFETY SHOWER AND EYE BATH .
OTHER PROTECTIVE CLOTHING.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
EXPLAN OF CARCIN:CARCINOGENS, 1994:ANTICIPATED TO BE CARCINOGEN.
ANIMAL:THYROID, LIVER. FIRST AID PROC:PROVIDED PERSON IS CONSCIOUS.
CALL A PHYSICIAN.

Melt/Freeze Pt:M.P/F.P Text:>302F,>150C
Appearance and Odor:SOLID.

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS, STRONG ACIDS, ACID CHLORIDES, ACID ANHYDRIDES,
ALUMINUM, COPPER, IRON AND IRON SALTS.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:TOXIC FUMES OF:CARBON MONOXIDE, CARBON
DIOXIDE, NITROGEN OXIDES.

Waste Disposal Methods:DISSOLVE OR MIX THE MATERIAL WITH A COMBUSTIBLE
SOLVENT AND BURN IN A CHEMICAL INCINERATOR EQUIPPED WITH AN AFTER
BURNER AND SCRUBBER. OBSERVE ALL FEDERAL, STATE AND LOCAL
ENVIRONMENTAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.